Sheet Metal Corrosion Testing: Salt Spray Test & ASTM B117钣金腐蚀测试完整指南:盐雾试验、ASTM B117 与评级判读

Most enclosure corrosion problems we get asked to fix are not coating problems. They are specification problems. A supplier sends a certificate that says "passed 1,000 h salt spray," the cabinet ships to a coastal substation, and red staining appears along the door hem within eighteen months. The coating very likely did everything the test asked of it. The test simply never asked the right question. This guide covers sheet metal corrosion testing from the manufacturing side: what the standards actually define, how to write a duration that means something, how to read a rating, and the eight mistakes that turn a passing report into field scrap.

Key Takeaways: Sheet Metal Corrosion Testing

  • ASTM B117 and ISO 9227 are method standards. Neither one sets a test duration or a pass/fail criterion — that comes from your product specification or drawing.
  • ISO 9227 defines three methods (NSS, AASS, CASS), not four. Cyclic corrosion testing lives in separate standards: ASTM G85, SAE J2334, GMW 14872, ISO 11997-1, IEC 60068-2-52.
  • "1,000 hours" is meaningless on its own. It only becomes a requirement when you attach a failure definition: no red rust, or red rust below a stated area, or a maximum scribe creep width.
  • Salt spray hours are not service years. Use ISO 9223 corrosivity categories plus ISO 12944 durability bands as the shared language instead.
  • A flat test coupon measures your coating system. A production-representative part measures your manufacturing system. First article should be the latter.

Why corrosion testing is a specification problem, not a lab errand

Nobody owns corrosion testing on a project. Purchasing wants a line for the PO. The structural engineer wants to know whether the sample in the chamber resembles the assembly that ships. Quality wants a report that survives an audit. Usually all three assume somebody else wrote it down.

In our experience reviewing first-article reports and incoming supplier certificates, the failure is almost never that a coating was badly applied. It is that the test request was so thin that almost any result could be called a pass. "Salt spray 1,000 h" written into a drawing with no specimen definition, no rating method and no failure threshold is not a requirement. It is a hope.

This guide is about the verification side of corrosion. If your question is "which coating system should I choose," start with our sheet metal coating selection guide instead. The dividing line is simple: if the verb in a paragraph is choose or compare coatings, it belongs there. If the verb is specify, run, rate or misjudge, it belongs here.

The three families of corrosion tests

Every accelerated corrosion test you are likely to see on an enclosure drawing falls into one of three families. Knowing which family a method belongs to is more useful than memorising its parameters, because the family tells you what the result can and cannot support.

Neutral salt spray (NSS) — the baseline

Continuous fog, constant temperature, constant chemistry. No drying stage, no UV, no mechanical damage. This is ASTM B117 and the NSS method of ISO 9227.

NSS is excellent at one thing: comparing like with like. Run two batches of the same part through the same chamber and the better one will usually win. That makes it a solid tool for supplier screening, batch-to-batch consistency checks and quick triage. It is a poor tool for predicting how long a cabinet will last outdoors, and the standards themselves warn against using it that way.

Acidified variants — AASS and CASS

Lower the pH with acetic acid and you get acidified salt spray (AASS). Add copper chloride and raise the temperature and you get the copper-accelerated acetic acid salt spray (CASS), covered by ASTM B368. These are harsher and produce visible results faster.

They exist mainly for decorative electroplated finishes — think copper-nickel-chromium stacks on trim and hardware. Using CASS to qualify an outdoor powder-coated steel enclosure is usually a category error: you are applying a decorative-plating screen to a barrier-protection system and then wondering why the numbers look alarming.

Cyclic corrosion testing (CCT)

Alternate a wet salt stage with high humidity and a drying stage, and repeat. That is cyclic corrosion testing. Representative methods include ASTM G85 (a family of modified salt spray procedures), SAE J2334 and GMW 14872 from the automotive world, ISO 11997-1 for paints and varnishes, IEC 60068-2-52 for environmental testing, and VDA 233-102 in the German automotive supply chain.

CCT costs more and takes longer per data point, but for coastal sites, de-icing salt exposure and long outdoor service it is the more honest test. The mechanism is explained in the section on why salt spray hours are not field years.

Family Typical methods Best used for Weak at
Neutral salt spray ASTM B117, ISO 9227 NSS Batch comparison, supplier screening, quick triage Life prediction, real-world ranking
Acidified (AASS / CASS) ISO 9227 AASS / CASS, ASTM B368 Decorative plated finishes, fast screening Outdoor barrier systems (frequent misuse)
Cyclic (CCT) ASTM G85, SAE J2334, GMW 14872, ISO 11997-1, IEC 60068-2-52 Coastal, de-icing salt, long outdoor service Cheap screening; slower and costlier

ASTM B117 vs ISO 9227: what actually differs

This is the question we get most often, and the answer is rarely what people want to hear: under neutral conditions the two standards are close enough that the choice seldom changes the outcome. What changes the outcome is the execution detail that nobody writes down.

Operating parameters side by side

Under neutral conditions the two are nearly identical: 5% NaCl, pH 6.5–7.2 measured at 25 °C, a 35 °C chamber, and a collection rate of 1.5 ± 0.5 mL per 80 cm² per hour. They differ mainly in specimen angle — 15–30° from vertical under ASTM B117 versus 15–25° under ISO 9227 — and in how the report documents execution.

Parameter ASTM B117 ISO 9227 (NSS)
Solution 5% NaCl by mass 5% NaCl (commonly expressed as 50 ± 5 g/L)
pH of collected solution 6.5–7.2, measured at 25 °C 6.5–7.2, measured at 25 °C
Chamber temperature 35 °C (a ±2 °C tolerance is commonly cited; confirm against the current edition) 35 °C (confirm tolerance against the current edition)
Fog collection rate 1.5 ± 0.5 mL per 80 cm² per hour (i.e. 1.0–2.0) 1.5 ± 0.5 mL per 80 cm² per hour (i.e. 1.0–2.0)
Specimen angle 15–30° from vertical 15–25° from vertical, ideally near 20°

Two cautions. First, chamber temperature tolerance and specimen angle differ between sources and between editions — some Chinese-language pages still quote 45° or 60°, which is wrong. Second, if you are quoting a standard on a drawing, quote the edition year too. "ASTM B117" with no year is a moving target.

ISO 9227 defines three methods, not four

ISO 9227 specifies three salt spray methods: NSS (neutral), AASS (acetic acid) and CASS (copper-accelerated acetic acid). It does not contain cyclic methods — a lot of published content gets this wrong. Cyclics are their own standards.

ISO 9227 method Solution pH Temperature
NSS 5% NaCl 6.5–7.2 35 °C
AASS 5% NaCl plus acetic acid 3.1–3.3 35 °C
CASS 5% NaCl plus acetic acid plus copper chloride 3.1–3.3 50 °C

Commonly cited crosswalks are NSS with ASTM B117, AASS with the acidified procedure in ASTM G85, and CASS with ASTM B368. Annex numbering inside ASTM G85 is a recurring source of disagreement between sources, so put the method name rather than the annex number on your drawing.

If you see an old German drawing calling up DIN 50021, that standard was superseded by ISO 9227 — worth updating the reference rather than arguing about equivalence. In the Chinese supply chain you will also meet GB/T 10125 (aligned with ISO 9227) and GB/T 2423.18 (aligned with IEC 60068-2-52).

Which one belongs on your drawing

Pick by market and by data history, not by rigour:

  1. North American end customer with an existing NSS database → ASTM B117.
  2. EU customer, or a coating supplier quoting ISO 12944 durability → ISO 9227 NSS.
  3. Any coastal, de-icing salt or long-outdoor-service application → add a cyclic method alongside, not instead.

Then write down the angle, the cleaning method and the rating standard. Those three details move results far more than the choice between B117 and 9227. For a broader view of what finishes you are choosing between, see surface finishing options for sheet metal enclosures.

Sample preparation: what makes a report survive audit

A corrosion report is only as good as the object you put in the chamber. This is the section most specifications skip, and it is where audit failures originate.

Flat coupon vs real part

A flat panel answers: is this coating system sound? A production part answers: is this manufacturing system sound? Those are different questions. The features that corrode first on a real enclosure are almost never present on a flat coupon:

Our recommendation: qualify with a production-representative part, or a sample panel that carries the real features. Use flat coupons for ongoing batch trend monitoring, where you want a stable reference rather than a pass/fail gate.

Two of the six features above are process outcomes rather than design features: how the weld and its heat-affected zone should be prepared, and how edge break and deburring change what the coating has to cover. Both are worth settling before you put anything in a chamber.

To scribe or not to scribe

A scribe is a deliberate scratch through the coating to the substrate. It is used to measure how far corrosion creeps sideways from the damage, evaluated per ASTM D1654.

Scribe when the question is adhesion and under-film propagation — comparing pretreatments, or checking whether a coating delaminates once breached. Do not scribe when the question is barrier integrity of an intact part; you have just created the failure you were testing against, and the result tells you little about an undamaged cabinet.

If you do scribe, specify the tool, the width, whether it crosses to bare metal, and the maximum creep distance. "Scribe creep ≤ 2 mm" with no scribe definition is not reproducible.

Placement, separation and post-test cleaning

Interim inspection and documentation

If you need a 1,000-hour result, plan interim checks rather than one look at the end. Keep each check short so the chamber does not drift, and record what you saw.

A report that will survive an audit should contain: standard number and edition year; specimen description with a unique identifier; solution concentration, pH, chamber temperature, collection rate, angle, and total duration; pre- and post-test photographs; and the secondary rating standards used. Missing any of those and the report is decorative. For how this fits into a broader incoming and in-process routine, see our quality control and inspection workflow.

Prepared sheet metal enclosure corrosion test specimens mounted at a controlled angle in a salt spray chamber, with cut edges, weld seams and fastener holes exposed
Powder coated sheet metal enclosure panels on a finishing line before corrosion testing, showing edge coverage and film build at formed corners

How many hours should you specify?

The standards deliberately don't tell you

This is the single most useful thing to understand. ASTM B117, ISO 9227 and JIS Z 2371 define how to run the fog. They do not define how long to run it, and they do not define what counts as failure. Duration and acceptance come from the product specification, the customer drawing, or an industry specification that cites the test method.

So "1,000 hours" is not a standard requirement. It is a convention that became a convention because someone's customer asked for it once.

Indicative hour bands by finish

The bands below reflect common industry practice across the sources we reviewed. They are not standard requirements, and any number you write into a PO should come from your product specification.

Finish Commonly specified band (indicative practice only)
Zinc plating, clear / blue passivate 96–168 h to white rust
Zinc plating, yellow / iridescent passivate 168–336 h
Hot-dip galvanising Several hundred to over 1,000 h
Powder coating on steel with pretreatment 500–1,000 h (some specifications go to 1,500 h)
E-coat (electrophoretic primer) Several hundred to 1,500 h
Anodising, standard or hard Several hundred hours
Duplex system (zinc plus paint) 1,000–3,000 h
Marine / offshore high-performance system 1,000 h and up

None of these figures appears in ASTM B117 or ISO 9227. Any number you write into a PO should come from your product specification. The bands also assume the substrate question is already settled, so read them alongside which base metal the environment actually points to.

If you are choosing between paint systems, our powder coating vs liquid painting comparison covers what each achieves on a real part, and for aluminium housings see aluminum anodizing for outdoor enclosures.

Hours alone mean nothing without a failure definition

Four thresholds appear again and again, and they are not interchangeable:

  1. No red rust anywhere on significant surfaces. The strictest common form.
  2. Red rust below a stated area percentage, often 5%, rated against ASTM D610 or ISO 4628-3.
  3. Scribe creep below a stated width, commonly in the 2–3 mm range, rated against ASTM D1654.
  4. Blistering rating at or above a stated level, rated against ASTM D714 or ISO 4628-2.

"500 h with no red rust" and "500 h with red rust under 5%" sound similar in a meeting and are very different gates in a chamber. Write the number and the rating standard.

Longer is not automatically better

Every extra week of chamber time is a week of schedule. If the specification says 500 h and you ask for 2,000 h, you have not bought four times the assurance — you have bought four times the wait and a result your coating supplier never designed for. If you want visibility into how degradation progresses, use interim inspections instead of extending the endpoint.

Reading the result: the rating standards that matter

Rusting on painted steel — ASTM D610 (0–10)

ASTM D610 grades rusting on painted steel from 10 (no rusting) down to 0. The correspondence below is the widely published scale; confirm it against the current edition of ASTM D610 before writing acceptance limits into a contract.

ASTM D610 grade Rusted area
10 ≤ 0.01%
9 > 0.01 – 0.03%
8 > 0.03 – 0.1%
7 > 0.1 – 0.3%
6 > 0.3 – 1.0%
5 > 1.0 – 3.0%
4 > 3.0 – 10.0%
3 > 10.0 – 16.0%
2 > 16.0 – 33.0%
1 > 33.0 – 50.0%
0 > 50.0%

Note the step most people miss: 5% rusted area sits in grade 4 (>3.0–10.0%), not grade 5 (>1.0–3.0%). A clause written "red rust ≤ 5%" therefore corresponds to roughly D610 grade 4, while a clause written "grade ≥ 5" is a stricter gate (≤3%) than the percentage it claims to implement. Write the percentage and the grade consistently.

ISO 4628 — the parts you will see in a corrosion report

ISO 4628-1 sets out the general system, with separate parts for each degradation mode: -2 blistering, -3 rusting (Ri 0 = none through Ri 5 = dense), -4 cracking, -5 flaking. Quoting "ISO 4628" without the part number is a common defect in supplier reports.

Metallic coatings — ISO 10289 (Rp / RA)

For plated parts ISO 10289 gives two numbers: Rp, the protection rating (how well the coating protects the base metal), and RA, the appearance rating. A part can protect well and look bad, or the reverse. If appearance matters, you need both on the report.

Blistering and post-exposure adhesion

ASTM D714 rates blisters by size and density together — a rating like "8-Few" means small blisters, few in number. ASTM D3359 (cross-cut adhesion) is often run after exposure to see whether the film has let go underneath.

A rough crosswalk, and its limits

ASTM D610 ISO 4628-3 Ri Reading
10–9 Ri 0–Ri 1 Essentially clean
8–6 Ri 2–Ri 3 Light, localised rusting
5 and below Ri 4–Ri 5 Significant to heavy rusting

Treat this as a coarse orientation, not an equivalence. ISO 4628-3 gives an approximate correlation to ASTM D610 in its annex on related rating systems (Ri 0↔10, Ri 1↔9, Ri 2↔7, Ri 3↔6, Ri 4↔4, Ri 5↔1–2); check the current edition — the 2016 edition has been withdrawn. The two standards assess different things under different procedures. Do not write a dual-limit requirement that assumes they are interchangeable.

One closing rule: a report that says only "pass," with no rating method and no numbers, is not a report. Ask for the rating standard and the measured value.

Salt spray hours are not field years

Why the correlation breaks

Constant wet salt fog is not any real atmosphere. Real service alternates wet and dry, cycles in temperature, adds UV, industrial pollutants, salt deposition that concentrates as water evaporates, and mechanical damage from handling and impact.

The drying stage matters more than people expect. Chloride concentration during drying drives pitting in a way that a permanently wet surface does not reproduce. A continuous-fog test has no drying stage at all, so it misses the mechanism that usually initiates real pitting. It is the same mechanism behind why chloride-driven pitting behaves differently in a washdown environment, where a cabinet is hosed down and left wet every shift.

What to use instead as a shared language

Two standards give you a vocabulary that survives translation between buyer, engineer and coating supplier:

So instead of asking for "1,000 hours," describe the target as a coating system rated for, say, C4 at high durability. That is still a relative ranking, not a warranty, but it connects to how coating systems are actually specified and it travels across languages. For a worked example on a real product, see how we write the environment clause in an EV charger enclosure enquiry.

For a concrete case of what this looks like on a real product, see our coastal EV charger enclosure study. And remember that corrosion and ingress ratings are different axes — a cabinet can pass a salt spray test and still leak. Keeping electrolyte out is the job of the gasket and sealing system that keeps the electrolyte out in the first place, not of the paint.

Why cyclic testing correlates better

Wet-dry cycling reproduces chloride concentration. Temperature cycling drives diffusion and coating stress. Swelling and shrinkage fatigue opens up marginal areas. Longer total programmes — weeks rather than days — capture slow degradation that a short fog run never reaches.

What neither test covers

Neither NSS nor CCT addresses UV degradation (see ASTM G154 and ISO 4892), nor mechanical damage and stone chipping (SAE J400). A complete outdoor coating qualification is a programme: corrosion, cyclic corrosion, weathering and mechanical damage, not one chamber run.

What are the most common salt spray testing mistakes?

These are the patterns we see when we review supplier certificates and our own first-article results. Each one produces a report that reads as a pass.

  1. Qualifying with a flat coupon, then shipping a formed and welded assembly. Edges, welds and holes never entered the chamber. Fix: first article on a production-representative part.
  2. Specifying hours with no failure definition. "1,000 h" satisfies any outcome. Fix: attach the rating standard and the threshold.
  3. Rating only the flat face. Corrosion starts at edges and around fasteners. Fix: state which surfaces are significant and rate those.
  4. Wiping the specimen before rating. You have removed the evidence. Fix: rinse gently, air dry, photograph, then rate.
  5. Running different metals in one chamber. Corrosion products migrate and contaminate. Fix: one material system per run.
  6. Confusing white rust with red rust. On zinc-coated steel, white rust is the sacrificial layer doing its job; red rust means the substrate is corroding. Fix: state which one your criterion refers to.
  7. Using salt spray to qualify a stainless steel enclosure. Stainless fails by pitting, crevice corrosion and galvanic coupling, none of which NSS represents well. See our stainless vs carbon steel comparison and galvanic corrosion between dissimilar metals.
  8. Accepting a report with no photographs, no angle, no collection rate, no edition year. It cannot be traced, so it cannot be disputed. Fix: put the required report fields in the PO.

A spec block you can paste into your RFQ

Edit the blanks; keep the structure. Putting this in the enquiry is the cheapest corrosion control you will ever buy.

  1. Test method: ASTM B117 ___ (edition) or ISO 9227 NSS ___ (edition) — state one.
  2. Duration: ______ hours, with interim inspections at ______ h intervals.
  3. Specimen: production-representative part including cut edges, welds and holes. If flat panel: state size, material and pretreatment.
  4. Scribe: yes / no. If yes: tool, width, to substrate, maximum creep ______ mm per ASTM D1654.
  5. Acceptance: no red rust on significant surfaces; or red rust ≤ ______ % rated per ASTM D610 grade ≥ ______ ; or ISO 4628-3 Ri ≤ ______ ; blistering per ASTM D714 ≥ ______ . Fill the percentage and the grade so they agree with the D610 table above — "≤ 5%" and "grade ≥ 5" are not the same gate.
  6. Post-test handling: rinse in clean water, air dry, photograph, then rate.
  7. Report must contain: standard with edition year, specimen ID and photos, solution concentration, pH, chamber temperature, collection rate, angle, total duration, and the rating standards used.
  8. Frequency: first article, then ______ per lot, then annual type testing.

For where this sits in the full sequence, see our enclosure qualification test plan; if the enclosure is going into a certified assembly, align the clause with UL 508A and IEC 61439 certification requirements.

What testing actually costs and takes in a Chinese supply chain

Three options, and they are not equivalent:

Route Typical use Trade-off
In-house chamber at the fabricator Process control, internal screening, trend monitoring Fast and cheap; not an independent certificate
Third-party laboratory (SGS, Intertek, Element and similar) Customer-required certificates, tender documents Independent and traceable; adds scheduling time and cost
Customer-nominated laboratory Regulated or contractual requirements Highest acceptance; longest lead time

There is also a price tag: where a corrosion test clause shows up in the unit price breaks down what chamber time and paperwork add to a part.

The schedule point is the one that bites. A 1,000-hour programme is roughly six weeks of continuous chamber occupancy — before the report is written. If your project timeline does not include that, the test will be the reason the shipment slips. Build it into enclosure lead time planning from the start, and position it correctly in the prototype-to-production workflow.

Practical notes from this side of the supply chain: confirm in the PO who issues the report and in what language; require photographs as part of the deliverable, not as a favour; and check that the report can be traced back to a specimen identifier that matches the part you received.

One limit belongs alongside everything above. Comparative work reported by the EU ENABLE project found that cyclic methods and neutral salt spray do not rank pretreatment systems in the same order. A figure quoted without the pretreatment identified therefore cannot be compared across two supplier offers — the argument is made in why salt spray hours alone cannot rank a pretreatment.

Frequently Asked Questions

Is ASTM B117 the same as ISO 9227?

Not identical, but under neutral conditions the operating parameters are close enough that results are broadly comparable. The differences that matter in practice are specimen angle, and whether the report records the execution details at all.

How many hours of salt spray do I need for powder-coated steel?

For powder-coated steel on a properly pretreated substrate, 500–1,000 h is the commonly specified band; some specifications go to 1,500 h. That band is industry practice, not a standard requirement — ASTM B117 and ISO 9227 set no duration — and it is meaningless without a stated failure definition.

How many hours of salt spray equals one year of outdoor exposure?

No fixed number exists, and no standard gives one. The standards themselves caution that salt spray results correlate poorly with long-term natural exposure, and published outdoor-versus-accelerated comparisons disagree by roughly an order of magnitude depending on site, material and method. Use ISO 9223 corrosivity categories and ISO 12944 durability bands to describe the target instead.

What is the difference between white rust and red rust?

On zinc-coated steel, white rust is zinc corrosion product — the sacrificial layer working. Red rust means the steel substrate itself is corroding. Your acceptance criterion must say which one it refers to.

Should I use CASS for an outdoor enclosure?

Usually not. CASS was developed for decorative electroplated finishes. For outdoor barrier systems, neutral salt spray and, better, a cyclic method are the more appropriate tools.

Is a cyclic corrosion test worth the extra cost?

If the product sits outdoors, near the coast, or anywhere de-icing salt is used, yes. Cyclic methods reproduce wet-dry cycling, which is the mechanism that drives real pitting and is absent from continuous fog.

Does ASTM B117 define pass/fail?

No. It defines how to run the fog — nothing more. Duration and acceptance criteria come from the product specification or drawing that cites it.

Where to go from here

Write the requirement before you write the drawing. Pick the method family that matches the service environment, choose the standard by market, then fill in the three things that actually determine whether the report means anything: the specimen, the rating method, and the failure definition. Done in that order, sheet metal corrosion testing is cheap insurance; done backwards, it is six weeks of chamber time and a certificate that proves nothing.

If you want a second pair of eyes on an existing test clause, send us the drawing and the specification. We run first-article corrosion checks as part of our prototype-to-production workflow, and we will tell you plainly when a clause is untestable before you pay for six weeks of chamber time.

Ready to specify an enclosure that will still look right after year five? Send us your 3D model and service environment for a free DFM review and a corrosion test recommendation.

A corrosion result and a coating defect are different failures — for the second, our powder coating defects guide starts from whether the defect follows the part or the batch.

我们被请去处理的钣金外壳腐蚀问题,绝大多数不是涂装问题,而是规范问题。供应商寄来一份证书,写着「通过 1000 小时盐雾」,机柜发到海边变电站,十八个月后门折边位置出现红锈。涂层很可能完成了测试要求它做的每一件事——只是这项测试从来没问对问题。本文从制造端讲钣金腐蚀测试:标准到底规定了什么、怎么写一个真正有意义的时长、怎么判读评级,以及八个把「合格报告」变成现场报废的错误。

核心要点:钣金腐蚀测试

  • ASTM B117 与 ISO 9227 都是方法标准。两者都不规定测试时长,也不规定合格判据——那部分来自你的产品规范或图纸。
  • ISO 9227 定义的是三种方法(NSS、AASS、CASS),不是四种。循环腐蚀试验另有标准:ASTM G85、SAE J2334、GMW 14872、ISO 11997-1、IEC 60068-2-52。
  • 「1000 小时」单独存在毫无意义。它只有在附上失效定义之后才成为要求:无红锈、或红锈面积低于某个百分比、或划痕蔓延宽度不超过某个值。
  • 盐雾小时数不是使用年数。改用 ISO 9223 腐蚀性等级加 ISO 12944 耐久性档位作为共同语言。
  • 平板试片测的是你的涂层体系,生产性零件测的是你的制造体系。首件应该用后者。

为什么腐蚀测试是规范问题,而不是实验室跑腿

项目里没人真正拥有腐蚀测试。采购要的是采购单上那一行字;结构工程师想知道箱子里那个样品像不像真正要出货的装配体;质量要的是一份经得起审核的报告。通常三方都以为另外两方已经写下来了。

我们复核首件报告和供应商来料证书的经验是:失败的原因几乎从来不是涂层涂得不好,而是测试委托书写得太薄,薄到任何结果都能被叫做合格。图纸上写一句「盐雾 1000 小时」,却没有试样定义、没有评级方法、没有失效门槛——那不是要求,那是一个愿望。

本文讲的是腐蚀的验证侧。如果你的问题是「该选哪种涂层体系」,请先看我们的涂层选型指南。分界线很简单:一段话里的动词是选或比涂层,归那边;是规定、执行、评级或误判,归这边。

腐蚀测试的三大家族

你在外壳图纸上可能看到的每一种加速腐蚀试验,都属于以下三族之一。记住一个方法属于哪一族,比背它的参数更有用,因为族别决定了这个结果能支撑什么、不能支撑什么。

中性盐雾(NSS)——基准线

连续喷雾,恒温,恒定化学环境。没有干燥阶段,没有紫外,没有机械损伤。这就是 ASTM B117,以及 ISO 9227 里的 NSS 方法。

NSS 只擅长一件事:同类比同类。把同款零件的两批放进同一个箱子,较好的那批通常会赢。因此它是供应商筛选、批次一致性检查、快速分诊的可靠工具。它不擅长预测机柜在户外能撑多久,标准本身也警告不要这样用。

酸化变体——AASS 与 CASS

用乙酸把 pH 降下来,得到酸化盐雾(AASS)。再加氯化铜并升高温度,得到铜加速乙酸盐雾(CASS),对应 ASTM B368。两者更严苛,出结果更快。

它们主要为装饰性电镀层而存在——比如装饰件和五金上的铜-镍-铬叠层。用 CASS 去鉴定户外粉末喷涂钢制外壳,通常属于类别错误:你把一套装饰性电镀的筛选方法,套在了一套屏障保护体系上,然后奇怪数字为什么难看。

循环腐蚀试验(CCT)

把湿盐阶段、高湿阶段与干燥阶段交替进行并重复,这就是循环腐蚀试验。代表性方法包括 ASTM G85(改良盐雾系列)、汽车行业的 SAE J2334 与 GMW 14872、涂料用 ISO 11997-1、环境试验用 IEC 60068-2-52,以及德国汽车供应链的 VDA 233-102。

CCT 更贵,单个数据点耗时更长,但对于海边站点、除冰盐环境和长期户外服役,它是更诚实的试验。背后的机理在后面「为什么盐雾小时数不等于现场年数」一节里解释。

家族 典型方法 最适合的用途 不擅长
中性盐雾 ASTM B117、ISO 9227 NSS 批次对比、供应商筛选、快速分诊 寿命预测、真实环境排序
酸化(AASS / CASS) ISO 9227 AASS / CASS、ASTM B368 装饰性电镀层、快速筛选 户外屏障体系(常被误用)
循环(CCT) ASTM G85、SAE J2334、GMW 14872、ISO 11997-1、IEC 60068-2-52 海边、除冰盐、长期户外服役 廉价筛选;更慢更贵

ASTM B117 与 ISO 9227:到底差在哪

这是我们被问得最多的问题,而答案通常不是提问者想听的:在中性条件下两者参数接近,选哪个很少改变结果。真正改变结果的是那些没人写下来的执行细节。

操作参数对照

在中性条件下两者几乎一致:5% 氯化钠,25 °C 下测得 pH 6.5–7.2,箱体 35 °C,沉降量 1.5 ± 0.5 mL/80 cm²·h。主要差别在试样角度——ASTM B117 是偏离垂直 15–30°,ISO 9227 是 15–25°——以及报告对执行细节的记录方式。

参数 ASTM B117 ISO 9227(NSS)
溶液 质量分数 5% 氯化钠 5% 氯化钠(常写作 50 ± 5 g/L)
收集液 pH 6.5–7.2,25 °C 下测得 6.5–7.2,25 °C 下测得
箱体温度 35 °C(±2 °C 为常见引用值,请对照现行版本确认) 35 °C(公差请对照现行版本确认)
沉降量 1.5 ± 0.5 mL/80 cm²·h(即 1.0–2.0) 1.5 ± 0.5 mL/80 cm²·h(即 1.0–2.0)
试样角度 偏离垂直 15–30° 偏离垂直 15–25°,理想接近 20°

两点提醒。第一,箱体温度公差与试样角度在不同来源、不同版本之间有差异——有些中文资料至今还写 45° 或 60°,那是错的。第二,图纸上引用标准时要把版本年份一起写上,光写「ASTM B117」是一个移动靶。

ISO 9227 定义三种方法,不是四种

ISO 9227 规定三种盐雾方法:NSS(中性)、AASS(乙酸)、CASS(铜加速乙酸)。它不包含循环方法——很多公开资料在这点上写错了。循环方法另有其标准。

ISO 9227 方法 溶液 pH 温度
NSS 5% 氯化钠 6.5–7.2 35 °C
AASS 5% 氯化钠加乙酸 3.1–3.3 35 °C
CASS 5% 氯化钠加乙酸加氯化铜 3.1–3.3 50 °C

常见的对应关系是 NSS 对应 ASTM B117、AASS 对应 ASTM G85 中的酸化程序、CASS 对应 ASTM B368。ASTM G85 内部的附录编号在不同来源之间长期存在分歧,所以图纸上写方法名,不要写附录号。

遇到引用 DIN 50021 的德国老图纸,该标准已被 ISO 9227 取代——与其争论等效性,不如直接更新引用。在中国供应链里你还会遇到 GB/T 10125(对应 ISO 9227)与 GB/T 2423.18(对应 IEC 60068-2-52)。

你的图纸该写哪一个

按市场和数据积累来选,而不是按严谨程度:

  1. 北美终端客户,且已有 NSS 数据库 → ASTM B117。
  2. 欧盟客户,或涂层供应商按 ISO 12944 耐久性报价 → ISO 9227 NSS。
  3. 任何海边、除冰盐或长期户外服役的应用 → 在盐雾之外再加一项循环方法,而不是替换掉它。

然后把角度、清洗方法和评级标准写下来。这三项对结果的影响,远大于 B117 与 9227 之间的选择。若想先看可选的表面处理范围,见钣金外壳表面处理方案。

试样制备:什么样的报告才经得起审核

腐蚀报告的好坏,取决于你放进箱子的那个东西。这一节是大多数规范会跳过的地方,也正是审核失败的源头。

平板试片 vs 真实零件

平板试片回答的是:这套涂层体系靠不靠谱? 生产零件回答的是:这套制造体系靠不靠谱? 这是两个不同的问题。真实外壳上最先腐蚀的位置,平板试片上几乎都不存在:

我们的建议:用生产性代表零件做鉴定,或者用一块带真实特征的样件板。平板试片留给日常批次趋势监控——那里你要的是一个稳定参照,而不是一道合格闸门。

上面六项里有两项属于工艺结果而非设计结果:焊缝及其热影响区该如何处理,以及倒角与去毛刺如何改变涂层需要覆盖的边缘。这两件事最好在把任何东西放进箱子之前就定下来。

划不划线

划痕是刻意划穿涂层直至基材的一道刻痕,用来测量腐蚀从损伤处横向蔓延多远,按 ASTM D1654 评定。

当问题是附着力和膜下蔓延时要划线——比如比较不同前处理,或检查涂层一旦破损会不会剥离。当问题是完好零件的屏障完整性时不要划线——你刚刚制造出了你正在测试的那种失效,结果说明不了完好机柜的任何事。

如果确实要划,请规定工具、宽度、是否划到裸金属,以及最大蔓延距离。只写「划痕蔓延 ≤ 2 mm」而不定义划痕,是不可复现的。

摆放、间隔与试验后清洗

中间检查与文件记录

如果你要的是 1000 小时的结果,就规划中间检查,而不是最后只看一次。每次检查要短,避免箱体状态漂移,并把看到的东西记录下来。

一份经得起审核的报告至少应包含:标准编号及版本年份;带唯一编号的试样描述;溶液浓度、pH、箱体温度、沉降量、角度与总时长;试验前后照片;以及所用的二级评级标准。缺任何一项,这份报告就只是装饰。关于它如何嵌入更大的来料与过程例行工作,见我们的质量控制与检验流程。

盐雾试验箱中按受控角度摆放的钣金外壳腐蚀试样,切边、焊缝与紧固件孔均暴露在外
腐蚀测试前涂装线上的粉末喷涂钣金外壳板件,可见边缘覆盖率与折角处的膜厚

该规定多少小时?

标准故意不告诉你

这是最值得理解的一点。ASTM B117、ISO 9227 和 JIS Z 2371 规定的是怎么喷雾。它们不规定喷多久,也不规定什么算失效。时长和验收来自产品规范、客户图纸,或引用该试验方法的行业规范。

所以「1000 小时」不是标准要求。它成为一个惯例,只是因为某位客户曾经这样要求过一次。

按镀层划分的参考小时带

下表是我们复核过的多份来源中常见的行业做法。它们不是标准要求,你写进采购单的任何数字都应来自你的产品规范。

表面处理 常见规定区间(仅为行业惯例参考)
电镀锌,白钝化 / 蓝钝化 96–168 h 至白锈
电镀锌,黄钝化 / 彩色钝化 168–336 h
热浸镀锌 数百小时至 1000 h 以上
钢件粉末喷涂(含前处理) 500–1000 h(部分规范到 1500 h)
电泳底漆 数百小时至 1500 h
阳极氧化,常规或硬质 数百小时
双重体系(镀锌加涂装) 1000–3000 h
船舶 / 海上高性能体系 1000 h 及以上

这些数字没有一个出现在 ASTM B117 或 ISO 9227 里。你写进采购单的任何数字都应来自你的产品规范。这些区间还默认基材问题已经定了,所以请配合环境实际指向哪种基体金属一起读。

如果你正在选择涂料体系,我们的粉末喷涂与液体涂装对比讲清了两者在真实零件上的表现;铝制壳体另见户外外壳的阳极氧化。

没有失效定义,小时数毫无意义

下面四种门槛反复出现,而且它们不能互换:

  1. 重要表面无红锈。 常见形式中最严格的一种。
  2. 红锈面积低于某个百分比,常见为 5%,按 ASTM D610 或 ISO 4628-3 评级。
  3. 划痕蔓延低于某个宽度,常见在 2–3 mm 区间,按 ASTM D1654 评级。
  4. 起泡等级不低于某个级别,按 ASTM D714 或 ISO 4628-2 评级。

「500 小时无红锈」和「500 小时红锈低于 5%」在会议上听起来差不多,在箱子里是两个差别很大的闸门。请把数字和评级标准一起写。

更长不等于更好

每多一周箱体时间,就是多一周工期。如果规范写 500 小时而你要求 2000 小时,你没有买到四倍的保证——你买到了四倍的等待,以及一个你的涂层供应商从未针对设计过的结果。如果你想知道劣化是怎么推进的,用中间检查,而不是把终点延长。

读懂结果:真正有用的评级标准

涂装钢材的锈蚀——ASTM D610(0–10)

ASTM D610 对涂装钢材的锈蚀从 10(无锈)一直评到 0。下表是公开资料中广泛引用的刻度;在把验收限值写进合同之前,请对照 ASTM D610 现行版本确认。

ASTM D610 等级 锈蚀面积
10 ≤ 0.01%
9 > 0.01 – 0.03%
8 > 0.03 – 0.1%
7 > 0.1 – 0.3%
6 > 0.3 – 1.0%
5 > 1.0 – 3.0%
4 > 3.0 – 10.0%
3 > 10.0 – 16.0%
2 > 16.0 – 33.0%
1 > 33.0 – 50.0%
0 > 50.0%

最容易踩错的一步:5% 的锈蚀面积落在 4 级(>3.0–10.0%),而不是 5 级(>1.0–3.0%)。 因此写成「红锈 ≤ 5%」的条款,大致对应 D610 4 级;而写成「等级 ≥ 5」的条款,实际是一个比它声称的百分比更严的闸门(≤3%)。百分比和等级要写一致。

ISO 4628——腐蚀报告里会出现的几个部分

ISO 4628-1 给出总纲,各降解模式分列不同部分:-2 起泡、-3 锈蚀(Ri 0 为无,至 Ri 5 为密集)、-4 开裂、-5 剥落。供应商报告里只写「ISO 4628」而不写部分号,是常见缺陷。

金属镀层——ISO 10289(Rp / RA)

对于电镀件,ISO 10289 给出两个数字:Rp 为保护等级(镀层保护基体的能力),RA 为外观等级。一个零件可以保护得很好却很难看,也可以反过来。如果外观重要,报告上两个都要有。

起泡与暴露后附着力

ASTM D714 同时按尺寸和密度评起泡——像「8-Few」这样的评级表示小泡、数量少。ASTM D3359(划格附着力)常在暴露后加做,用来判断漆膜下面是否已经脱开。

粗略对照及其局限

ASTM D610 ISO 4628-3 Ri 判读
10–9 Ri 0–Ri 1 基本干净
8–6 Ri 2–Ri 3 轻微、局部锈蚀
5 及以下 Ri 4–Ri 5 显著到重度锈蚀

这只是粗略定位,不是等价关系。ISO 4628-3 在其关于相关评级体系的附录中给出了与 ASTM D610 的近似对应(Ri 0↔10、Ri 1↔9、Ri 2↔7、Ri 3↔6、Ri 4↔4、Ri 5↔1–2);请核对现行版本——2016 版已被撤销。两项标准在不同程序下评估的是不同的东西。不要写出一条假定两者可以互换的双重限值要求。

最后一条规矩:一份只写「合格」、没有评级方法和数字的报告,不是报告。要评级标准和实测值。

盐雾小时数不等于现场年数

相关性为什么会断

恒定湿盐雾不是任何一种真实大气。真实服役是干湿交替、温度循环,外加紫外、工业污染物、随水分蒸发而浓缩的盐分沉积,以及搬运和冲击带来的机械损伤。

干燥阶段比人们想象的更重要。干燥过程中的氯离子浓缩会以某种方式驱动点蚀,而永久湿润的表面无法复现这种机制。连续喷雾试验根本没有干燥阶段,所以它错过了通常引发现场点蚀的那个机理。这也正是冲洗环境下氯离子点蚀表现不同的原因——那里的机柜每个班次都要被水冲一遍然后湿着放那儿。

该用什么作为共同语言

有两项标准提供了一套能在采购、工程与涂层供应商之间翻译的词汇:

所以与其要求「1000 小时」,不如把目标描述成一套按 C4、高耐久性评级的涂层体系。这仍然是相对排序,不是质保,但它接上了涂层体系真正的规格方式,而且能跨语言流通。关于在真实产品上长什么样,见我们的海边充电桩外壳案例。也别忘了腐蚀与防护等级是两条不同的轴——一台机柜可以通过盐雾测试,同时照样漏水。把电解液挡在外面,是密封胶条与密封系统的工作,不是油漆的工作。

为什么循环试验相关性更好

干湿循环复现了氯离子浓缩。温度循环驱动扩散与涂层应力。溶胀与收缩疲劳会撕开临界部位。总周期更长——以周而非天计——能捕捉到短时喷雾永远到不了的缓慢劣化。

两种试验都覆盖不到的

NSS 和 CCT 都不涉及紫外老化(见 ASTM G154 与 ISO 4892),也不涉及机械损伤与石击(SAE J400)。一套完整的户外涂层鉴定是一个项目组合:腐蚀、循环腐蚀、耐候与机械损伤,而不是一次箱体试验。

最常见的盐雾测试错误有哪些?

以下是我们复核供应商证书和自家首件结果时反复看到的模式。每一种都会产出一份读起来像合格的报告。

  1. 用平板试片做鉴定,然后发运折弯焊接的装配体。 切边、焊缝和孔从来没进过箱子。改法:首件用生产性代表零件。
  2. 只规定小时数,没有失效定义。「1000 h」可以满足任何结果。改法:附上评级标准和门槛。
  3. 只评平面。 腐蚀从边缘和紧固件周围开始。改法:写明哪些表面是重要表面,并评这些面。
  4. 评级前擦拭试样。 你把证据擦掉了。改法:轻冲、吹干、拍照,然后评级。
  5. 把不同金属放进同一箱。 腐蚀产物会迁移并污染。改法:一箱一种材料体系。
  6. 把白锈当红锈。 在镀锌钢上,白锈是牺牲层在干活;红锈说明基体在腐蚀。改法:写明你的判据指哪一个。
  7. 用盐雾去鉴定不锈钢外壳。 不锈钢的失效形式是点蚀、缝隙腐蚀和电偶耦合,NSS 哪一种都代表不好。见不锈钢与碳钢外壳对比与异种金属电偶腐蚀。
  8. 接受一份没有照片、没有角度、没有沉降量、没有版本年份的报告。 它无法追溯,因此无法质疑。改法:把报告应含字段写进采购单。

可以直接粘进询价单的规范条款

改掉空格,保留结构。把这一段放进询价,是你买得到的最便宜的腐蚀控制。

  1. 试验方法:ASTM B117 ___(版本)或 ISO 9227 NSS ___(版本)——二选一。
  2. 时长:______ 小时,中间检查间隔 ______ 小时。
  3. 试样:生产性代表零件,含切边、焊缝与孔。若用平板:写明尺寸、材料与前处理。
  4. 划痕:是 / 否。若是:工具、宽度、是否至基材、最大蔓延 ______ mm(按 ASTM D1654)。
  5. 验收:重要表面无红锈;或红锈 ≤ ______ %(按 ASTM D610 等级 ≥ ______);或 ISO 4628-3 Ri ≤ ______;起泡按 ASTM D714 ≥ ______。填写时让百分比与等级和上文 D610 表格一致——「≤ 5%」与「等级 ≥ 5」不是同一道闸门。
  6. 试验后处理:清水冲洗、吹干、拍照,然后评级。
  7. 报告须含:标准及版本年份、试样编号与照片、溶液浓度、pH、箱体温度、沉降量、角度、总时长,以及所用评级标准。
  8. 频次:首件,之后每批 ______,再之后年度型式试验。

关于它在完整序列中的位置,见我们的外壳鉴定试验计划;如果外壳要装进认证装配体,请把条款与 UL 508A 与 IEC 61439 认证要求对齐。

在中国供应链里,测试到底要花多少钱、多少时间

三条路线,并不等价:

路线 典型用途 权衡
加工厂自有盐雾箱 过程控制、内部筛选、趋势监控 快且便宜;不是独立证书
第三方实验室(SGS、Intertek、Element 等) 客户要求的证书、投标文件 独立可追溯;增加排期与成本
客户指定实验室 法规或合同要求 认可度最高;周期最长

它也有价格:腐蚀测试条款在单价里体现在哪拆开了箱体时间与文件工作给一个零件增加了多少。

最咬人的还是工期。1000 小时的试验约等于连续占用箱体六周——这还没算写报告。如果你的项目排期里没有这一段,测试就会成为发货延误的原因。请从一开始把它纳入外壳交期规划,并在样机到量产流程里放在正确的位置。

来自供应链这一侧的几条实操提示:在采购单里写明谁出报告、用什么语言;把照片列为交付物的一部分,而不是人情;并确认报告能追溯到一个与你收到的零件匹配的试样编号。

上面所有内容之外,还有一条限制值得并排放着。欧盟 ENABLE 项目的对比报告发现,循环试验与中性盐雾给出的前处理排序并不一致。因此一个没有标明前处理工艺的数值,无法在两家供应商的报价之间横向比较——论证见为什么仅看盐雾小时数无法给前处理排序。

常见问题

ASTM B117 和 ISO 9227 是一回事吗?

不完全一样,但在中性条件下操作参数接近,结果大体可比。实践中真正有影响的差别是试样角度,以及报告到底有没有记录执行细节。

粉末喷涂钢件需要多少小时盐雾?

前处理到位的前提下,粉末喷涂钢件常见规定区间是 500–1000 小时,部分规范到 1500 小时。 这个区间是行业惯例而非标准要求——ASTM B117 和 ISO 9227 都不规定时长——而且没有失效定义时它毫无意义。

多少小时盐雾等于一年户外暴露?

没有一个固定数字,也没有标准给出过。标准本身就警告盐雾结果与长期自然暴露相关性差,而且已发表的户外与加速老化对比随地点、材料和方法不同相差约一个数量级。请改用 ISO 9223 腐蚀性等级与 ISO 12944 耐久性档位来描述目标。

白锈和红锈有什么区别?

在镀锌钢上,白锈是锌的腐蚀产物,说明牺牲层在工作。红锈说明钢基体本身在腐蚀。你的验收判据必须说明它指的是哪一个。

户外外壳应该用 CASS 吗?

通常不该。CASS 是为装饰性电镀层开发的。对于户外屏障体系,中性盐雾,以及更好的循环方法,才是合适的工具。

循环腐蚀试验值得多花钱吗?

如果产品放在户外、靠海,或任何使用除冰盐的地方,值得。循环方法复现了干湿交替,而干湿交替正是引发现场点蚀的机理,连续喷雾里没有它。

ASTM B117 规定合格判据吗?

不规定。它只规定怎么喷雾,没有更多。 时长和验收判据来自引用它的产品规范或图纸。

下一步

先写要求,再画图纸。挑一个与服役环境匹配的试验族,按市场选标准,然后填上真正决定报告有没有意义的三件事:试样、评级方法、失效定义。按这个顺序做,钣金腐蚀测试就是便宜的保险;反过来做,就是六周箱体时间和一份什么都证明不了的证书。

如果你想让第二双眼睛过一遍现有的测试条款,把图纸和规范发给我们。我们在样机到量产流程里做首件腐蚀检查,并且会在你为六周箱体时间付钱之前,直白地告诉你哪一条条款根本没法测。

想让外壳在第五年之后依然好看? 把你的 3D 模型与服役环境发给我们,免费获得一次 DFM 评审和一份腐蚀测试建议。

腐蚀试验结果与涂层缺陷是两类不同的失效——后者请看我们的粉末涂层缺陷指南,它从「缺陷跟着零件走还是跟着批次走」入手。

Get the Test Clause Right Before You Pay for Chamber Time在为箱体时间付钱之前,先把测试条款写对

Send the service environment, the enclosure drawing and the volume you are qualifying for. We will return a corrosion test clause with the specimen, the rating method and the failure definition filled in, the indicative hour band for your finish system, and a fixed-price quotation for the sample build within 24 hours.把服役环境、外壳图纸和你要鉴定的数量发给我们。24 小时内回一份填好试样、评级方法与失效定义的腐蚀测试条款、适配你涂层体系的参考小时区间,以及样机制作的固定价报价。